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@PeterTaylor If I calculated correctly, Nate's answer implies that $ \binom{2n}{n}_q > \binom{2n}{n-a}_q \cdot q^{a^2} $, which means that the sum of the other coefficients is $ 2 \sum_{a=1}^n \binom{2n}{n-a}_q < 2 \binom{2n}{n}_q \sum_{a=1}^n q^{-a^2} < 2 \binom{2n}{n}_q \sum_{a=1}^\infty q^{-a^2} $. Since $ 2 \sum_{a=1}^\infty q^{-a^2} < 1 $ for any $ q \geqslant 3 $, the middle coefficient is larger than the sum of all the others when $ q \geqslant 3 $. For $ q = 2 $ this is perhaps not true, but taking into account the residues I am interested in, this case also holds.
@LSpice To your first question - I don't know :) To your second question - yes, selecting some vector twice would mean that the condition of linear independence is violated. I'll edit my question to clarify.