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The number of smooth projective toric Fano varieties is known up to dimension 9 by work of Mikkel Øbro, cf. sequence A140296 in OEIS. No formula or good upper bound seems to be known.
I don't have a reference, but the same argument as for $\mathbb{R}$ should work: Let $F$ be any field of characteristic $0$. Then $G=\text{SL}_2(F)$ acts on $V=F^2$. The action of $G$ on the symmetric square $S^2(V)$ gives a homomorphism $G\rightarrow \text{SL}_3(F)$ with kernel $\{\pm 1\}$, and choosing the right basis, the image preserves the quadratic form $x^2+y^2-z^2$. This gives the desired isomorphism $\text{PSL}_2(F) \stackrel{\cong}{\longrightarrow} \text{SO}(2,1)(F)$.