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The classification of finite simple groups is very interesting for a couple of reasons at least. The formulation required the list of sporadic groups to be complete; and the empirical approach of the discoverers of sporadic groups was important to the acceptance that the list was right. I remember the champagne for J4 ...
@Gerry Myerson An early example is Jacobi saying that Dirichlet is the only really rigorous mathematician around; and juxtaposing that with his use of Fourier series in prime number theory (books.google.co.uk/books?id=tqaWlHIsZXAC&pg=PA29). By the time you have G. H. Hardy commenting on Ramanujan and the complex zeroes of the Riemann zeta function, I believe the thought had become a commonplace.
It's more complicated than that (Dynin wasn't the first to add something about the paper). But I have moved two paras off the page and onto the talk page so that they can be discussed.