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Oh, sorry I did not see you comment! Unfortunately I don't have a concrete and clear motivation. I found this question interesting in it self (at least for me). I would love to hear the answer to your second question too!
In your first question there was two questions. 1) Morita invariance imply dependence only on derived categories? 2)Cannot different algebras have equivalent derived categories without having equivalent categories of modules
I'm not sure I understand your remarks. 1) Here, It is about derived Morita equivalences. 2) The point is that we are considering differential graded algebras and not only algebras.
Wonderful, Thank you for the reference! Just for the future reader: the total classification is summarized in pages 129-131. The answer is: There is 19 geometries in dimension 4!