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Many thanks for your nice answer and a reference. In the cases $D = 4$, $(2,2)$ and $D = 6$, $(3,3)$ there are also examples of flat spin manifolds $M^2$ and $M^3$, respectively, where $M = \mathbb R^{(1,1)}_{*}/Z_2 $. The orginal problem for me was to find examples of: i) 5-dimensional Riemannian Ricci-flat spin manifold with only one parallel spinor and ii) 6-dimensional pseudo-Riemannian Ricci-flat spin manifold with either only one parallel spinor or two parallel spinors of opposite chiralities. So the chance is small, but it will be analysed using your classification.