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Thank you very much for your answer and would you like to explain a little bit about "the additive chain complex groups are not the place to study this as the singular complex given as a simplicial set enables the full structure to be exhibited explicitly."? Are additive chain complex and singular complex the same thing?
I'm not sure what do you mean by "$K$-orbits" here. If $G$ is complex semisimple and $K$ is the maximal compact subgroup, it is well-known that the $K$-action on $G/B$ is also transitive, hence the $K$-orbit is $G/B$ itself. Maybe what you really mean is the isotropy group of the $K$-action.
Thank you very much for your answer! I think the tensor product you constructed using $U$ is a kind of "twisted tensor product", which is analogous to the twisted D-module in D-module theory, isn't it?