Let $N$ be a Riemannian manifold, denote $R$ its purely covariant Riemann curvature tensor with sign convention so that the sectional curvature is $K(X,Y) = R(X,Y,X,Y)$ for an orthonormal pair.
Consider the complexified tangent space $TM \otimes \mathbb{C}$ and the complex-linear extension of $R$, which we still denote $R$. By definition, $N$ has *nonpositive Hermitian sectional curvature* if $R(X, Y, \bar{X}, \bar{Y}) \leqslant 0$ for all $X, Y \in TM \otimes \mathbb{C}$.
Obviously, nonpositive Hermitian sectional curvature is stronger than nonpositive sectional curvature.
**QUESTION.** Is nonpositive Hermitian curvature *strictly* stronger than nonpositive curvature?
In other words, are there examples of Riemannian manifolds with nonpositive sectional curvature, but not nonpositive Hermitian sectional curvature?
I expect the answer easily yes, in fact it is claimed in e.g. [1] or [8], but I couldn't find an example in the relevant literature, e.g. [1][2][3][4][5][6][7][8][9].
NB: Yau-Zheng [8] showed that the answer is no for manifolds with negative $\delta$-pinched sectional curvature with $\delta \geqslant 1/4$. According to [9, Theorem 9.26], the answer is no for Kähler surfaces.
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**FOLLOW UP QUESTIONS**
Following (almost) the terminology of Siu [6], a Riemannian manifold with nonpositive Hermitian sectional curvature has *strongly nonpositive curvature*. He also introduces *very strongly nonpositive curvature*: Consider the curvature operator
$$
\begin{aligned}
Q \colon \otimes^2 TM \times \otimes^2 TM \to \mathbb{R}
\end{aligned}
$$
such that $Q$ is defined for decomposable tensors by $Q(X\otimes Y, Z \otimes W) = R(X , Y, Z , W)$. $N$ has *very strongly nonpositive curvature* if $Q(\sigma, \sigma) \leqslant 0$ for all $\sigma \in \otimes^2 TM$. In other words, the curvature operator is negative semidefinite.
In this case, the complex-linear extension of $Q$ is still negative semidefinite, which clearly implies that $M$ has strongly nonpositive curvature.
**Question 2.** Is there an example showing that very strongly nonpositive curvature is strictly stronger than strongly nonpositive curvature?
Finally, there is a notion of (very) strongly negative curvature for Kähler manifolds, but it's not simply something like $Q(\sigma, \sigma) < 0$ for all nonzero $\sigma$. Indeed, still denoting $Q$ its complex-linear extension, we have $Q(\sigma, \bar{\sigma}) = 0$ for any $\sigma$ of type $(2,0)$ or $(0,2)$, e.g. $X \otimes Y$ with $X, Y \in T^{1,0} M$. $N$ has *very strongly negative curvature* if $Q(\sigma, \bar{\sigma}) < 0$ for all nonzero tensors $\sigma \in T^{1,0} M \otimes T^{0,1} M$, and $N$ has *strongly negative curvature* if $Q(\sigma, \bar{\sigma}) < 0$ for all nonzero tensors $\sigma \in T^{1,0} M \otimes T^{0,1} M$ of length $\leqslant 2$, e.g. $\sigma = X \otimes \bar{Y} + Z \otimes {\bar{W}}$.
It is clear that
$$\text{very strongly negative} ~\Rightarrow~ \text{strongly negative} ~\Rightarrow~ \text{negative sectional curvature}$$
**Question 3.** Are there examples proving that the converse implications are false?
Again, according to [9, Theorem 9.26], the answer is no for Kähler surfaces.
Remark: Of course, there are similar notions of (very) strong nonnegative / positive curvature and one could ask the same questions.
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[1] J. Amorós, M. Burger, K. Corlette, D. Kotschick, and D. Toledo. Fundamental groups of compact Kähler manifolds. 1996.
[2] Eells and Lemaire. Two reports on harmonic maps. 1995
[3] Jost and Yau. Harmonic mappings and Kähler manifolds. 1983.
[4] Mostow and Siu. A compact Kähler surface of negative curvature not coveredby the ball. 1980.
[5] Ohnita and Udagawa. Stability, complex-analyticity and constancy of pluriharmonic maps from compact Kaehler manifolds. 1990.
[6] Siu. The complex-analyticity of harmonic maps and the strong rigidity of compact Kähler manifolds. 1980.
[7] Xin. Geometry of harmonic maps. 1996
[8] Yau and Zheng. Negatively $\frac14$-pinched Riemannian metric on a compact Kähler manifold.
[9] F. Zheng, Complex differential geometry, 2000.