$\newcommand{\Psh}{\operatorname{Psh}}
\newcommand{\Sh}{\operatorname{Sh}}
\newcommand{\op}{{\operatorname{op}}}$
Let $X$ be a locale, $X^\op$ the corresponding frame.

1. What's the localic reflection of $\Psh X$?

We know that
$$
X^\op \cong \mathrm{Sub}_{\Sh X}(1)
$$
Call $Y = \mathrm{Sub}_{\Psh X}(1)$ the localic reflection of $\Psh X$.
In particular, one has $\Psh X \cong \Sh Y$.

Since $\Sh X$ is a subtopos of $\Psh X$, $X$ should be a sublocale of $Y$, i.e. there should be a nucleus $j$ on $Y^\op$ such that $X^\op = Y^\op / j$.

2. Who's $j$?