As a first pass, we can approximate the odds of landing on a face by projecting the polyhedron on a sphere, and taking the fraction of the sphere which it covers. [![polyhedron][1]][1][![projection][2]][2] Then the odds of a triangular, square or pentagonal roll overall are $$14.4\%,\ 50.4\%,\ 35.1\%$$ and the odds for an individual triangular, square or pentagonal face are $$0.72\%,\ 1.68\%,\ 2.93\%.$$ This is Simpson's method. It also represents the result of throwing the die high above an adhesive surface, so that the die is well-randomized in the air, and then after touching the surface falls onto the nearest side. The angles have exact formulas which are easy enough to calculate in Mathematica: data = PolyhedronData["SmallRhombicosidodecahedron"]; faces = Map[data[[1, 1]][[#]] &, data[[1, 2, 1]]]; angle[a_, b_, c_] := 2 ArcTan[Abs[a.Cross[b, c]]/ (Norm[a] Norm[b] Norm[c] + a.b Norm[c] + b.c Norm[a] + c.a Norm[b])]; Map[Length[#] angle[# // Mean // Simplify, #[[1]], #[[2]]] &, faces] // FullSimplify // Union This gives the following solid angle measures for each triangular, square or pentagonal face: $$6 \cot^{-1}\left(2 \sqrt{3} u+\sqrt{124 u-61}\right),\\ 8 \cot^{-1}\left(2u+\sqrt{40 u-21}\right),\\ 10 \cot^{-1}\left(2 \sqrt{5u}+3 \sqrt{2u+1}\right)$$ where $u=5+2\sqrt{5}$. [1]: https://i.sstatic.net/Cu8qsm.png [2]: https://i.sstatic.net/mInPym.png