As I mentioned in my comment, I recall this concept as the "time-ordered exponential" (from Quantum Field Theory lectures, long ago). Alternatively, the "path-ordered exponential". I'm no expert here, so I can't really point you to any definitive sources that you couldn't find with a bit of searching yourself anyway. Actually, f(t) does not have to be particularly 'nice', just locally integrable should be enough. You can go even further and replace f(t)dt by dF(t) for a continuous finite-variation function F. In fact, F can be any continuous semimartingale, as long as you use Stratonovich integration in the associated SDE (as Ito integration is not coordinate independent). This is the method used by Rogers & Williams (Diffusions, Markov Processes and Martingales) to construct Brownian motions on lie groups and referred to there as the *product integral injection*. Also, why restrict to lie groups/algebras? Any manifold with an affine connection will do, where f maps to the tangent space at some base point, and is moved along the generated curve by parallel transport. In the case of Lie Groups, there is a standard connection which gives you the time-ordered exponential.