One relationship is that the number of $p$-singular elements ( that is, elements whose order is divisible by $p$) is divisible by the number of Sylow $p$-subgroups of $G$. This is a consequence of a theorem Frobenius, together with Sylow's theorem, though I don't recall seeing the fact stated in print. 
     Let $P$ be a Sylow $p$-subgroup of $G.$ Frobenius proved that if $n$ divides the order of  finite group $G,$ then the number of solutions of $g^{n}=1$ in $G$ is an integer multiple of $n.$ Hence the number of solutions of $x^{[G:P]} = 1$ in $G$ is divisible by $[G:P].$
This number is also $|G| - \#$ ($p$-singular elements of $G$). Hence the number of $p$-singular elements of $G$ is divisible by $[G:P]$. This is in turn divisible by $[G:N_{G}(P)],$ which is the number of Sylow $p$-subgroups of $G.$