One of the most well known classes of Kähler-Einstein manifolds, i.e. complex manifolds which carry a Kähler metric $g$ such that $Ric_{g}= \lambda \cdot g$ $c\in\mathbb{R}$, are the generalized flag manifolds $$G^{\mathbb{C}}/P\cong G/K$$ of a compact connected simple Lie group. Here $P$ is a parabolic subgroup of the complexification $G^{\mathbb{C}}$ of $G$, and $K=p\cap G$ is the centralizer of a torus $S\subset G$, i.e. $K=C(S)$. If $S=T=$maximal torus, then we obtain a full flag manifold $G/T$.
Inside the class of generalized flag manifolds, we find a very important subclass of Kähler-Einstein manifolds, the (isotropy irreducible) Hermitian symmetric spaces $M=G/K$ of compact type (i.e. compact symmetric spaces endowed with a Hermitian structure invariant under the symmetries. In particular, this Hermitian structure is Kähler). It is well known that such a space $M=G/K$ admits a unique (as isotropy irreducible) Kähler-Einstein metric. Let me mention two basic facts for isotropy irreducible Hermitian symmetric spaces $M=G/K$:
The isotropy subgroup $K$ has an 1-dimensional center.
They are the only generalized flag manifolds which are the same time symmetric spaces.
A (generalized) flag manifold is a homogeneous Kähler manifold (the Kähler structure corresponds to the Kirillov-Kostant-Souriau symplectic form, since any flag manifold can be viewed as an adjoint orbit of an element in the Lie algebra of $G$). In particular, flag manifolds exhaust all compact and simply-connected homogeneous Kähler manifolds $M=G/K$ corresponding to a compact, connected, simple Lie group $G$. Their classification is based on the painted Dynkin diagrams.
Any coset $M=G^{\mathbb{C}}/P=G/K$ $(K=C(S))$ admits a finite number of invariant complex structures. Moreover, for any such complex structure we can define (a unique) homogeneous Kähler--Einstein metric, which is given in terms of the so-called Koszul form $$2\delta_{\frak{m}}=\sum_{\alpha\in R^{+}\backslash R_{K}^{+}}\alpha.$$ Thus, a flag manifolds admits a finite number of Kähler-Einstein metrics. Note that if some of the invariant complex structures are equivalent, then, the Kähler-Einstein metrics corresponding to these complex structures would be isometric.
More information about the geometry of flag manifolds, painted Dynkin diagrams, invariant Kähler-Einstein metrics, etc, can be found in the following articles:
D. V. Alekseevsky: Flag manifolds, in Sbornik Radova, 11th Jugoslav. Geom. Seminar. Beograd 6 (14) (1997) 3--35.
D. V. Alekseevsky and A. M. Perelomov: Invariant Kähler-Einstein metrics on compact homogeneous spaces, Funct. Anal. Appl. 20 (3) (1986) 171--182.