I claim that there are only countably many fssc centralisers.  It clearly suffices to show the same with ‘reductive’ in place of ‘semisimple’; I guess we can call that ‘frc’.  First note that, if $\mathfrak g$ is reductive and $x$ is an element of $\mathfrak g$ with Jordan decomposition $x = x_\text s + x_\text n$, then $\mathfrak m \mathrel{:=} \mathfrak g^{x_\text s}$ is reductive, and $\mathfrak g^x$ equals $\mathfrak m^{x_\text n}$.  It thus suffices to show that there are only countably many isomorphism types of centralisers of nilpotent elements in an frc Lie algebra.  First note that, since an frc Lie algebra is classified by the dimension of its centre and the root datum of its derived subalgebra, there are only countably many frc Lie algebras.  Since each frc Lie algebra has only finitely many nilpotent orbits under the associated adjoint group, we have shown the claim.

@YCor's [answer](https://mathoverflow.net/a/165697) to https://mathoverflow.net/questions/165656/how-many-three-dimensional-real-lie-algebras-are-there shows that there are uncountably many isomorphism types of 3-dimensional complex Lie algebras.  Thus, uncountably many of them are not fssc centralisers.