This question can be interpreted in two different ways.
Which Kahler manifolds admit a Kahler metric that is at the same time Einstein?
Which Kahler manifolds admit an Einstein metric?
If you want 1), then you need to start with a manifold whose canonical bundle is either a) ample (like hypersurfaces of degree $\ge n+2$ in $\mathbb CP^n$), or b) trivial (Calabi-Yau), c) is dual to an ample line bundle - Fano case.
In a) and b) there is always a Kahler-Einstein metric by a theorem of Aubin and Yau. In the case c) we get a very subtle question, which is expected to be governed by Yau-Tian-Donaldson conjecture. But all homogenious varieties are Kahler-Einstein.
If you want 2), then the amount of Einstein metrics clearly becomes much larger. For example, $\mathbb CP^2$ blown up in one or two point do not admit a Kahler-Einstein metric, but they do admit an Einstein metric. For a reference to this statement you can check the article of Lebrun http://arxiv.org/abs/1009.1270
At the same time it was speculated, that starting from real dimension 5 each manifold admits an Eistein metric.