I did a little computer search and I think I found an example of an odd immaculate group.
I searched for groups of the form $G=(C_q \rtimes C_p) \times C_N$ with odd primes $p,q$ such that $p | q-1$ and $N$ an odd integer satisfying $(N,pq)=1$. Using Tom's notations and results, we have
\begin{equation*} \frac{D(G)}{|G|} = \frac{D(C_q \rtimes C_p)}{|C_q \rtimes C_p|} \cdot \frac{D(C_N)}{|C_N|} = \frac{1+q+pq}{pq} \cdot \frac{\sigma(N)}{N} \end{equation*} where $\sigma(N)$ denotes the sum of divisors of $N$. We want $\frac{\sigma(N)}{N} = \frac{2pq}{1+q+pq}$. Since the last fraction is irreducible, $N$ has to be of the form $N=(1+q+pq)m$ with $m$ odd. I found the following solution :
\begin{equation*} p=7, \quad q=127, \quad m=393129. \end{equation*} This gives the immaculate group $G=(C_{127} \rtimes C_7) \times C_{399812193}$, which has order $|G| = 355433039577 = 3^4 \cdot 7 \cdot 11^2 \cdot 19^2 \cdot 113 \cdot 127$.