My recollection is that Macintyre proved there are $2^{\aleph_0}$ complete theories of pairs
$(K,L)$ where $L\subset K$ are real closed fields. This is in his thesis but I don't think
he published it anywhere else.  There are later papers of Francoise Delon and Walter Bauer
that develop this further.  On the other hand there is an earlier theorem of Robinson's that
if $L\subset K$ are real closed and $L$ is dense in $K$ then the theory of $(K,L)$ is decidable.