Consider the symmetric matrices associated to orthogonal reflections of the Euclidean plane. Since a line comes back to itself after a half-turn, you get a family indexed by $[0,\pi]$ describing a closed path in the set of symmetric matrices. A corresponding eigenvector of eigenvalue $1$ and norm $1$, deformed continuously goes into its opposite. We get thus a closed path (of symmetric matrices) which does not give rise to closed paths of associated eigenvectors.