Let $C_n = \frac{1}{n+1}\binom{2n}{n}$ be the $n$-th Catalan number, counting, for example, the number of (rooted) triangulations of the $(n+2)$-gon.
Let $P_n$ be the number of three-connected planar graphs on $n$-vertices, https://oeis.org/A000944.
If I am not mistaken, $C_{n-3} \leq P_n$ for $n\geq 4$. Eg., there are $C_2=2$ triangulations of the $4$-gon, and $2$ three-connected planar graphs on $5$ vertices.
Is there a nice injection?