Zhen Lin points out below that I've been way too cavalier with transferring model structures along a reflection. So the following answer is not clearly correct. I will leave this up as community wiki because I still think it addresses the spirit of the question, showing that spaces can be "modeled" in some sense by globular sets (or even just by graphs).
Contrary to my guess in the comments, the answer is no: there does exist a model structure on globular sets (reflexive or otherwise) which is Quillen equivalent to the Kan-Quillen model structure on spaces.
To see this, note that if $\mathcal A$ is a reflective subcategory of $\mathcal B$, and if $\mathcal A$ has a model structure, then the model structure transfers to $\mathcal B$, and the resulting adjunction is a Quillen equivalence.
Now, as mentioned in the comments, the category $Gph$ of graphs (reflexive or otherwise) is a reflective subcategory of $Glob$. Moreover, the category $Pos$ of posets is a reflective subcategory of $Gph$. Thus $Pos$ is reflective subcategory of $Glob$. So it will suffice to find a model structure on $Pos$ which is Quillen equivalent to topological spaces. This is proven by Raptis, by transferring the Thomason model structure on $Cat$.