Let $\Sigma$ be a symmetric positive definite matrix. Then the Cholesky decomposition gives us  $\Sigma=LL'$ where $L$ is lower triangular and unique.

Is there ever a second symmetric positive definite matrix $\Omega$ which is NOT diagonal that satisfies $\Sigma=\hat{L} \Omega \hat{L}'$? If so, is such a decomposition always available and if not under what conditions does such an $\Omega$ exist?