The distribution of the spacings of the eigenvalues of the GUE matrix $B$ is given by the <A HREF="https://en.wikipedia.org/wiki/Wigner_surmise">Wigner surmise</A>,
$$p(s)=(32s^2/\pi^2) \exp \left(-4 s^2/\pi\right),$$
where the spacing $s>0$ of adjacent eigenvalues is measured is units of the mean spacing. The spacing distribution of the sum $A+B$, with $A$ a fixed symmetric matrix, is assumed to be well described by $p(s)$. There is some evidence for that, see <A HREF="https://arxiv.org/abs/math-ph/0006020">Universality of the local spacing distribution in certain ensembles of hermitian Wigner matrices</A>. 

Eigenvalues that are not adjacent are only weakly correlated, I will assume that different spacings are independent. Then the expectation value of the minimal spacing $s_{\rm min}$ for $n\times n$ matrices is given by
$$\mathbb{E}[s_{\rm min}]=\int_0^\infty [1-c(s)]^n\,ds,$$
with $c(s)=\int_0^s p(s')ds'$ the cumulative spacing distribution. This integral does not have a closed form expression, below is a plot up to $n=100$. It should be possible to compute the large-$n$ asymptotics, I have not done that.

<IMG SRC="https://ilorentz.org/beenakker/MO/smin.png" WIDTH="400"/>

Plot of $\mathbb{E}[s_{\rm min}]$ versus $n$.