I don't think there is a reasonably short explicit description of non-Gorenstein curves. They could be described as lacking some of those conditions that define Gorenstein curves.
In any case, here is a simple example: Let $C$ be the union of three coordinate axis in $\mathbb A^3$. Then $C$ is not Gorenstein. It is probably a good exercise for you to check that this is true.
What I find fascinating about this is that the union of three lines contained in $\mathbb A^2$ is a Gorenstein curve, so this shows that being Gorenstein or not could depend on very subtle details.
Of course, $C$ can be projected to a plane and if the projection is general, then it will be one-to-one on $C$ and an isomorphism on each component to their respective images, however, it is not an isomorphism on $C$. This follows from the fact that the image of $C$ is Gorenstein, or more directly from the fact that the Zariski tangent space of $C$ is $3$-dimensional while that of its image is $2$-dimensional, so they can't be isomorphic.
(In case you are worried that this example is reducible, then think about how to get this singularity on an irreducible curve).