I think this should be called the *relatively ample cone* and its closure the *relatively nef cone*. Yes, this already exists and is sensible. This dissertation might be somewhat useful (although things are done for smooth $X$ instead of singular $X$). [UMich dissertation][1] [1]: http://deepblue.lib.umich.edu/bitstream/2027.42/60794/1/ofelguei_1.pdf