I don't know if this is the optimal, but an isosceles triangle with base and height $\sqrt{2}$ overlaps $2 \left(\sqrt{2}-1\right) \approx 0.828427$ when placed as below, and so improves over $\frac{3}{4}$:
[![SquareTri][1]][1]
I don't know if this is the optimal, but an isosceles triangle with base and height $\sqrt{2}$ overlaps $2 \left(\sqrt{2}-1\right) \approx 0.828427$ when placed as below, and so improves over $\frac{3}{4}$: