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Counterexample: let $k=7$, and let $B$ be the circulant matrix with $B_{ij}=1$ iff $i-j \in \{1,2,4\} \bmod 7$. Then $X_B$ is $I + \frac12 J$, with characteristic polynomial $(x-1)^6 (x-\frac92)$. Or use $B+I$ instead to get $I + \frac13 J$, with characteristic polynomial $(x-1)^6 (x-\frac{10}{3})$.