A graph is vertex transitive if $x \mapsto y$ by an automorphism. Let $P$ denote the stronger property that $x \mapsto y \mapsto x$ by an automorphism.
Simple facts:
$P \rightarrow$ unimodular. Just plug in the definition of unimodular to see why.
Cayley $\not \rightarrow P$. Free product $\mathbb Z_2 * \mathbb Z_3$ is an example.
$P \not \rightarrow$ Cayley. Petersen graph is an example.
Questions:
For the last claim, is there an infinite connected example?
Is there a common name for this propery $P$? I looked a bit and didn't find it.
Thanks!