**First using Brouwer**

Let $w\in \mathcal{V}_k$, necessarily $\zeta(w)$ is a bounded function since $\phi_k $'s are also bounded. The Lax-Milgram lemma implies there is a unique function $\widehat{w}\in  \mathcal{V}_k$
such that 
\begin{align}
\int_\Omega\nabla\widehat{w}\nabla\phi +\zeta(w)\widehat{w}\phi -f\psi dx=0\quad\text{for all}\quad\phi\in \mathcal{V}_{k}.
\end{align}

The Poincar\'{e}--Friedrichs inequality yields
\begin{equation}
\int_\Omega|\nabla\widehat{w}|^2dx  + \int_\Omega \zeta(w )\widehat{w}^2\, d x\leq \|f\|_{L^{2}(\Omega)}\,\|\widehat{w}\|_{L^{2}(\Omega)}\leq  C\|f\|_{L^{2}(\Omega)}\, \|\widehat{w}\|_{H_0^1(\Omega )} 
\end{equation}

Thus, letting $R=C\,\|f\|_{L^{2}(\Omega)}$, since $\varphi\geq0 $ we obtain the following estimates
\begin{align}\label{eq:boundedmapT}
&\|\widehat{w}\|_{H_0^1(\Omega )}\leq R
\quad\text{ and }\quad
 \int_\Omega \zeta(w )\widehat{w}^2\,dx\leq R^2.
\end{align}
We let $ \mathcal{B}_R=\big\{ w\in \mathcal{V}_k: \|w\|_{H_0^1(\Omega)} \leq R\big\}$, be the closed ball in $\mathcal{V}_k$ of radius $R$ centered at the origin.  Clearly, the mapping $T:\mathcal{V}_k\to \mathcal{B}_R$ with $Tw=\widehat{w}$  is well defined. 

It remains to prove that $T$ is a continuous mapping. Indeed, let
$\{w_n\}$ be a sequence in $\mathcal{V}_k$ with $w_n= \lambda_{1,n}\phi_1+\cdots+  \lambda_{k,n}\phi_k$ converging in $\mathcal{V}_k$ to a function $w= \lambda_1\phi_1+\cdots+  \lambda_k\phi_k$; i.e., $\lambda_{\ell,n}\xrightarrow{n\to\infty } \lambda_\ell$, $\ell=1,2,\cdots,k$. 
By continuity we have $ \varphi(w_n)\xrightarrow{n\to \infty}\varphi(w)$ almost everywhere. In addition, the convergence in $L^2(\Omega)$ also holds, since the continuity gives $\sup_{n\geq 0} \|\varphi(w_n) \|_{L^\infty(\Omega)} <\infty$ because $\sup_{n\geq 0}\|w_n\|_{L^\infty(\Omega) } <\infty$. 

On the other side, in virtue of  the first estimate above the sequence 
$\{Tw_n\}$ is bounded in finite dimensional space $\mathcal{V}_k$ and thus converges $\mathcal{V}_k$ up to a subsequence  to some $w_*\in \mathcal{V}_k$. Altogether, it follows that, for all  $\phi\in \mathcal{V}_k\subset L^\infty(\Omega)$ 
%
\begin{align*}
(f,\phi)= \lim_{n\to \infty} \int_\Omega\nabla\widehat{w}_n\nabla\phi  
+\zeta(w_n)\widehat{w}_n\phi dx=
\int_\Omega\nabla\widehat{w}\nabla\phi  +\zeta(w)w_* \phi. 
\end{align*}

The uniqueness of $\widehat{w}$ entails  $w_*=\widehat{w}=Tw$ and hence  the whole sequence $\{Tw_n\}$ converges in $Tw$ in $\mathcal V_k$, which gives the continuity of $T$. 

Therefore, by the Brouwer fixed-point theorem,  $T$ has a fixed point $v_k\in \mathcal V_k$, i.e., $v_k=Tv_k$ which clearly satisfies  the announced relation. 


**An alternative.** 

The given problem is equivalent to the minimization problem
 \begin{align}
 \mathcal{J}(v_k)=  \min_{v\in \mathcal{V}_k}  \mathcal{J}(v)\quad \text{with}\quad  \mathcal{J}(v):=  \frac12 \int_\Omega|\nabla v|^2 dx + \int_\Omega G(v)d x + \int_\Omega fvd x
 \end{align}
and we define the function $G(v)=  \int_0^v\zeta(\tau)\tau d \tau $.  Note that $G$ is non-negative since $\zeta(\tau)\geq 0$ and that $\mathcal J$ is continuous on $\mathcal V_k$. Using the Poincaré-Friedrichs inequality we find that $\mathcal{J}(v)\to \infty$, as $\|v\|_{L^2(\Omega)} \to \infty$ and $v\in \mathcal{V}_k$. Which implies the existence of a minimizer $v_k\in \mathcal{V}_k$ of \mathcal{J}, since we are in finite dimension space.