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Yemon Choi
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The volume of the unit ball for the spectral norm in nxn real matrices is given by the formula

$$ c_n \int\limits_{[-1,1]^n} \prod_{i < j} |x_i^2-x_j^2| dx_1\dots dx_n $$

where $c_n = n! 4^{-n} \prod_{k=1}^n v_k^2$

and $v_k=\pi^{k/2}/\Gamma(1+k/2)$ is the volume of the unit ball in R^n.

A much more general formula for calculating all kind of similar quantities appears e.g. here (Lemma 1). The proof is by applying the SVD decomposition as a change of variables.

The first values are

  • 2/3 π2 for 2x2 matrices
  • 8/45 π4 for 3x3 matrices
  • 4/1575 π8 for 4x4 matrices ...

There might be a closed formula for the integral above. Edit : such a formula appears in Armin's post below !!