I believe I have an example but you should check the details of whether it works. Maybe GAP can be used.
Let $X=\{1,2,3,4,5\}$ and $X'=\{1',2',3',4',5'\}$. Let $a,b\colon X\to X$ be given by $$a=\begin{pmatrix} 1 & 2 & 3& 4 &5\\ 2& 3& 3 &4& 5 \end{pmatrix}\qquad b=\begin{pmatrix} 1 & 2 & 3& 4 &5\\ 4& 5& 4 &4& 5 \end{pmatrix}.$$ Let $T=\langle a,b\rangle$ where we view $a,b$ as functions acting on the right of $X$. Then one checks $a\neq a^2=a^3$, $b^2=b$, $ba=b$ and I suppose these are defining relations.Anyway $T=\{a,a^2,b,ab,a^2b\}$. In particular $T^2$ is a band and $T^2\neq T$. Crucial is that $ab\neq a^2b$.
Let $T'=\langle a',b'\rangle$ be the dual semigroup obtained by reversing the multiplication of $T$. So $a'b'=b'$ and still $a'\neq (a')^2=(a')^3$, $(b')^2=b'$. Also $b'a'\neq b'(a')^2$. We view $T'$ as functions acting on the left of $X'$ in the obvious way (replace $i$ by $i'$ for each $i$ in $X$ to get $a',b'$ from $a$ and $b$). Let $\overline {T}$ be the subsemigroup of $T'\times T$ generated by $(a',a)$ and $(b',b)$. It has $11$ elements and satisfies $\overline{T}^2$ is a band, $\overline{T}^2\neq \overline{T}$ and $\overline{T}$ is self-dual via the obvious involution. $\overline{T}$ almost acts faithfully on the left of itself except that elements of the form $(b'a',t)$ and $(b'(a')^2,t)$ act the same for any $t\in \{b,ab,a^2b\}$.
To remedy that let $R=X'\times X$ with the rectangular band multiplication $(i,j)(k,l)=(i,l)$. Then $S=\overline T\cup R$ is a semigroup using the products in $\overline{T}$ and $R$ already defined and by putting $(u,v)(i,j)=(u(i),j)$ and $(i,j)(u,v)=(i,jv)$ for $u\in T', v\in T$, $i\in X'$ and $j\in X$. So $R$ is the minimal ideal of $S$. Note $S^2$ is a band, $S^2\neq S$ and still $S$ is self-dual (using the obvious involution on $X'\times X$ and the involution on $\overline{T}$).
Because $T'$ acts faithfully on the left of $X'$ we can now distinguish $(b'a',t)$ and $(b'(a')^2,t)$ (with $t$ as above) by the action on the left of $R$. Clearly if $i\neq k$ then $(i,j)$ and $(k,l)$ do not act the same on the left of $R$. On the other hand if $\{j,k\}\neq \{2,3\}$, then $(i,j)(a',a)=(i,ja)\neq (i,ka)=(i,k)(a',a)$. On the other hand $(i,2)(b',b)=(i,5)\neq (i,4)=(i,3)(b',b)$. Thus the action of $S$ on the left of itself is faithful. Note that $S$ has $36$ elements.
I hope this is correct and helps.