We use the idea suggested by Alekk.
Let $A_{i,j}$ the entries of $A$. Then in the first case, the entries of $M:=A+G$ are Gaussian independent random variables, that is, $M_{i,j}\sim N(A_{i,j},1)$. Denote $N$ the set of elements of $\Bbb R^{n^2}$ such that the matrix of generic term $x_{i,j}$ is not invertible. This set has null Lebesgue measure in $\Bbb R^{n^2}$ as it's the zeros of a polynomial. By independence, the family $(M_{i,j},i,j\in [n])$ is Gaussian, so $$p:=P(A+G\mbox{ is not invertible})=P((M_{i,j})_{i,j=1}^n\in S).$$
As the law of $(M_{i,j},i,j\in [n])$ is absolutely continuous with respect to Lebesgue measure in $\Bbb R^{n^2}$, we conclude that $p=0$.
In the second case, write $\det(A+G)$ as a polynomial of the $G_{i,j},i\leqslant j$, and use the fact that $(G_{i,j},1\leqslant i\leqslant j\leqslant n)$ is Gaussian to conclude in the same way as in the first case.
- The result doesn't depend on the choice of the matrix $A$.
- We don't need i.i.d.ness, just the fact that $(G_{i,j},i,j\in [n])$ is Gaussian in the first case, $(G_{i,j},i\leqslant j,i,j\in [n])$ in the second.