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Interesting question. You might want to have a look at the following books...

  • Marshall: Positive polynomials and sums of squares
  • Prestel: Positive polynomials
  • Bochnak, Coste, Roy: Real algebraic geometry
  • Basu, Pollack, Roy: Algorithms in real algebraic geometry
  • Knebusch, Scheiderer: Einführung in die reelle Algebra
  • Andradas, Bröcker, Ruiz: Constructible sets in real geometry

...and the following articles...

Also the so-called "S-procedure" could be of interest for you.