An identity $E$ that obeys all the claimed properties is
$$ E: x+(y+z) = (x+y)+w \hbox{ for all } x,y,z,w.$$

 - $E$ is implied by triple constancy (and hence by constancy): obvious since both sides are constant in this case
 - $E$ does not imply triple constancy (and hence does not imply constancy either): follows from considering the [left-zero semigroups][1] $x+y=x$ mentioned by arsmath
 - $E$ implies associativity: obvious by specializing to $w = z$
 - $E$ is not implied by associativity: follows from considering (say) addition on the integers

This candidate $E$ was located by pursuing the analysis in Pace's answer to isolate the form that $E$ had to take as much as possible, as described in the comments to that answer.  With a little more effort, it should be possible to entirely classify (up to relabelings and symmetries) the full set of identities $E$ that answer the question.

  [1]: https://en.wikipedia.org/wiki/Null_semigroup#Left_zero_semigroup