In characteristic zero, the group algebra is semisimple, so there are finitely many simple representations. These representations correspond to the blocks in the decomposition as a product of matrix algebras. As for characteristic p, this is modular representation theory, The number of irreducibles is the number of $p$-regular conjugacy classes (where $p$-regular means the period is prime to $p$). See, e.g., Serre's Linear Representations of FInite Groups.
Akhil Mathew
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