The differential of the exponential map on a symmetric space can be expanded (abusing some notation) as
$d{\rm Exp}_X=\sum_{n=0}^{\infty}\frac{({\rm ad}X)^{2n}}{(2n+1)!}.$
This is an old (1958) result of Helgason.
Question (EDITED): Is there any generalization to reductive homogeneous spaces?