Is the Duflo map for Lie algs. unique ? The Duflo map is the map S(g) -> U(g), which known to satisfy the following properties:
1) identity on g
2) isomorphism of g-modules (and in particular vector spaces)
3) restricted to Poisson center on S(g) it is ISOMORPHISM of commutative algebras
S(g)^g to ZU(g) (the center of U(g)).
(This is highly non-trivial property). It predicts that the centers on the "classical" and "quantum" level are the same. (Kontesevich generalized to arbitrary Poisson variety).
The question:
Is it the only map satisfying such properties ?
(At least for semisimple Lie algebras) ?
(I think answer is YES, and it should be known, but I have not seen the reference).
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Example let g-commutative, then it is true:
Since S(g)=U(g) and since the map is required to be identity on g and it is homomorphism,
so it  is identity map  on the S(g).
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If you read this question I guess you know what S(g) and U(g) means :) 
But may be nevertheless to keep good spirit of MO it is more polite  to include definitions:
S(g) - means commutative algebra - symmetric algebra of g (i.e. just take some basis xi in g and consider polynomial algebra C[x1 ... xn] - this is S(g) as a vector space. Lie algebra g acts on - it simple way - it acts on xi by adjoint action, and continued further by Leibniz rule).
U(g) - means NON-commutative algebra - universal enveloping algebra of g - which is: you take basis xi and consider non-commutative polynomials C[xi] where generators satisfying the relations: [xi, xj] = C_ij^k x_k , where  C_ij^k - are structure constants of g.
The  Duflo map is for example discussed here:
D. Calaque, C. Rossi "Lectures on Duflo isomorphisms in Lie algebras and complex geometry"
http://people.mpim-bonn.mpg.de/crossi/LectETHbook.pdf
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Kontsevich mentions that in general situation (of Poisson manifolds) Grothendieck-Teichmuller groups should act on quantizations and in particular on "Duflo" type maps, but he writes that for semisimple algebras this action is trivial. So we should not have problem  from this side. Moreover as far as I understand since nobody seen non-trivial example of this action it might be always like this.
 A: Choose a map $\varphi$ satisfying these properties and make the difference $\psi=\varphi^{-1}\varphi_D$ with the Duflo map. Then $\psi$ is an automorphism of the $\mathfrak g$-module $S(\mathfrak g)$ which is the identity on $\mathfrak g$ and is multiplicative on invariants. 
If you want this map to be universal (namely it should only involve universal formulae in terms of the Lie bracket) then it is very likely to be unique. 
But if you want the statement to be true independantly for every single Lie algebra, I would believe the answer is "no". Namely, consider the $2$-dimensional solvable Lie algebra $\mathfrak g:={\bf k}x\oplus {\bf k}y$ with $[x,y]=y$. Now we have that $S(\mathfrak g)={\bf k}[x,y]$ and that $S(\mathfrak g)^{\mathfrak g}={\bf k}$. Therefore any non-trivial automorphism of the $\mathfrak g$-module $S^{\geq2}(\mathfrak g)$ (e.g. a non-trivial multiple of the identity) gives a counter-example. . 
A: Well, a look at These notes of Calaque and Rossi would suggest (Remark 1.3) that the answer is no: $e^{\mathrm{tr}(ad)}$ is an automorphism of $S(\mathfrak{g})$, precomposing with this automorphism you get a different Duflo isomorphism. They call it modified Duflo element. We just need to check that the automorphism is the identity on $\mathfrak{g}$, which seems to be true if $\mathfrak{g}$ is unimodular (in particular if $\mathfrak{g}$ is semisimple). 
Edit: oops, the notes I'm attaching are also mentioned in your post, so I might be wrong cause you obviously read them. Ahh I see, it seems that the whole $e^{tr(ad)}$ is the identity in the unimodular case. 
