The limit exists for the first two examples that come to mind, namely topological entropy on the full shift and on certain simple Markov shifts.
If $X \subset \Sigma_d^+ = \{1,2, \dots, d\}^{\mathbb{N}}$ and $\sigma$ is the shift map, then for the topological entropy the quantity $a_n$ denotes the number of words of length $n$ that appear in some sequence $x\in X$. If $X$ is the full shift, then $a_n = d^n$, the entropy is $h = \log d$, and we quickly see that $a_n / e^{nh} = 1$ for all $n$.
Slightly more interesting is when you have a Markov shift, say $X\subset \Sigma_2^+$ determined by the transition matrix $\begin{pmatrix} 1 & 1 \\ 1 & 0 \end{pmatrix}$.
In this case it's not hard to show that the sequence $a_n$ is actually the Fibonacci sequence, and thus writing $\phi = \frac {1+\sqrt 5}2$ and $\psi = \frac { 1-\sqrt 5}2$, we have
$$
a_n = \frac 1{\sqrt 5} (\phi^{n+2} - \psi^{n+2}).
$$
Since $|\psi|<1$, this shows that the limit of $a_n / e^{nh}$ exists.
My guess is that a similar argument works for other Markov shifts and shows that the limit exists in those cases, based on obtaining a recurrence relation for $a_n$ and then an exact formula using standard tools for solving such sequences.
All that said, it's not immediately clear what the significance of the limit is, and I don't know of any name for it. For other interesting shifts, such as sofic shifts or shifts with specification, I'd be surprised if the limit always exists.
What is certainly quite important is to have conditions under which the ratio $a_n / e^{nh}$ is bounded away from $0$ and $\infty$. Such estimates are a significant part of arguments on the uniqueness of a measure of maximal entropy (and more generally uniqueness of equilibrium states), in particular the proof that such a measure satisfies a Gibbs property. For example, see Bowen's 1975 paper "Some systems with unique equilibrium states". (Dan Thompson and I also struggled with this not too long ago in Section 5.1 of this paper.)
It turns out that in the general setting, one of those bounds is immediate -- the sequence $a_n$ is submultiplicative, and so it's not hard to show that $a_n \geq e^{nh}$ for all $n$, whatever other properties the shift space has. Getting an upper bound on $a_n / e^{nh}$ is harder and requires some sort of specification property.