K.S. Brown has shown that much of abstract homotopy theory can be carried out in the setting of Brown (co)fibration categories [MR0341469]. The decisive property, immediate from the axioms, is that any morphism can be factored into a cofibration, followed by a weak equivalence.

H.-J. Baues [MR0985099], Cisinski [MR2729017] and Radulescu-Banu [arxiv.org/abs/math/0610009] then followed a similar path. Now someone wants to convince me that this is the proper setting for abstract homotopy theory. To begin with, I do like the simplicity of the axioms. Still, I'd like to be convinced of the practical necessity of this approach. Therefore my question:

Are there examples of Brown (co)fibration categories that are not already Quillen model categories?

More precisely, does there exist a pair (C,W) consisting of a category C and a subset W in Mor C (weak equivalences) such that (C,W) can be equipped with the structure of a Brown fibration (or cofibration) category, but not with the structure of a Quillen model category?

I would particularly be interested in examples in which the lifting axioms of Quillen are the obstacle. If they fail to be a Quillen model category just because they lack limits or colimits, I would be less enthusiastic.

On the other hand, I would also welcome examples in which it is relatively easy to show that they are Brown, but relatively hard that they are Quillen.

I would also welcome good general stability properties. For instance, in the Brown case there are no big problems if you want to enlarge the set of weak equivalences, as long as the larger set satisfies (2 of 3) and as long as the resulting larger set of acyclic cofibrations is stable under pushouts (incision).

To summarise, I want to be able to exclaim: "Good that we have the Brown apparatus!"