[EDITED by Y. Choi - I have attempted to paraphrase the original question into something a bit terser and more precise; if this is not what the original poster intended, they should make corrections themselves.]
Let $G$ be a locally compact abelian (LCA) group and let $f\in L^1(G)$. Can we always find $g\in L^2(G)$ such that $h=f-g$ lies in $L^1(G)\cap B(G)$, where $B(G)$ is the Fourier-Stieltjes algebra of $G$?
($B(G)$ consists of all Fourier transforms of complex-valued regular Borel measures on $\Gamma$, the dual group of $G$.)
If there are counterexamples, are there counterexamples with $G={\mathbb R}^n$?
In the case $G={\mathbb R}^n$, as we know, the Calderon-Zygmund decomposition theorem asserts that every $f\in L^1({\mathbb R}^n)$ is the sum of its good part $g$ and bad part $b$. Since $g$ is bounded and belongs to $L^1({\mathbb R}^n)$, it is not hard to verify that $g$ belongs to $L^p({\mathbb R}^n)$ for every $p\ge 1$. But it is easy to see that there exists an $f$ such that the inversion formula of Fourier transform fails for $b$. That is to say, the Calderon-Zygmund decomposition is not the decomposition of $L^1({\mathbb R}^n)$ that I want.