I have a feeling that the answer is yes, that the representation is unique for
infinitely many $n$, despite the computational evidence.
Perhaps others will be similarly compelled by the observations below.
Fixing $n$, the idea is to find a subset $P$ of ${1,...,n}$ so that
$\prod_{i \in P} i + \sum_{i \in P} i = n(n+1)/2 = T$. It is clear that $P$ has at
least two elements which are not 1 and at most $O(\log(n))$ elements. It takes a little work to show that $\sum_{i \in P} i \lt 3n/2 + O(1)$. Rewriting $\prod_{i \in P} i = p$, and being a little sloppy, $p$ must then be in or near $[n(n-2)/2 , T - \epsilon_1]$ where
$\epsilon_1$ is $O(\log(n)^2)$. So a computer search might do well to find all numbers
in this interval with factors no larger than $n$. Further, if $p > T - d$,
then $p$ must factorize into a product of numbers each smaller than $d$
One can go a little further and show that, if the largest factor has size
$n^\alpha$, then the sum has size smaller than $(2/\alpha)n^\alpha$, so if $p$ is far
enough away from $T$ then the largest element of $P$ can't be too small.
Other arguments show that if $(n-k) \in P $ for $k$ somewhat smaller than $n/2$, then there are at most one or two choices for $p$; this might be turned into a proof that $k$ cannot be in $[2,.., n/2 - \epsilon_2]$.
UPDATE 2011.02.23
Let's consider how often a partition contains (for fixed $k$) the value $n-k$ in
the product. Since $k=0$ and $k=1$ are realized infinitely often, let's try
$k \gt 1$.
$(n-k)*p + (n-k) + s = n(n+1)/2$, where $p$ and $s$ are the product, respectively
sum, of the members of the set $P - \{n-k\}$, that is all members in the set for
product which are not equal to $n-k$ . Now $s$ can range from some number
greater than $\log_2(p)$ up to $p+1$, as $s$ is the sum of distinct positive integers
whose product is the integer $p$. Further, $n(n+1)/2 \le (n- k+1) (p+1)$, so
$p \ge (n+k-2)/2$. So when $k$ is small ($k \lt \sqrt(n+1)-1$)
there aren't too many choices for $p$:
$(n+k-2)/2 \le p \lt (n+k-1)/2 + (k^2 +k)/2(n-k)$ .
So when $(k^2 + 2k) \lt n$, if $n+k$ is even, then $p$ could be $(n+k-2)/2$,
otherwise $n+k$ is odd and then $p$ could be $(n+k-1)/2$.
Now we can solve for
$s$: if $n+k$ is odd, $s = ( k^2 +k )/2$, otherwise $s = (k^2 + 2k -n)/2 \lt 0$
because $k$ is small.
So when $k$ is small, $s$ is one of only finitely many possibilities, which means
$p$ and therefore $n$ is one of only finitely many possibilities. Thus, when
$k$ is fixed and not $0$ or $1$, $n-k$ can occur in a partition
for only finitely many $n$. However, one can fix $k$, determine $s$,
find an additive partition of $s$,
multiply that partition to find $p$ and then find $n$, so there are many more
$n$ for which there is more than one partition.
I still suspect that there
are infinitely many $n$ for which there is not more than one partition. I also think
that one can extend the above analysis for $k$ up to $n/4$ to find out exactly
when $n-k$ is in a partition, but I'll let someone else run with that for now.
END UPDATE 2011.02.23
Once one finds a candidate $p$ that meets the conditions above, one still has
to find a factorization of $p$ such that $p$ plus the sum of these factors adds
up to $T$. I think there are enough primes and other obstacles to support
the answer yes. Further, I suspect the number of such representations is
bounded or if not bounded, grows slower than $\log(\log(n))$.
Gerhard "Ask Me About System Design" Paseman, 2011.02.16