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$\begingroup$The function $f(a):=a+\sin(a)$ maps the interval $[0,\pi]$ into itself, keeping fixed the endpoints. Moreover $f(a) > a$ for $0 < a < \pi$. So any starting point $0 < a_0 \le \pi $ generates an increasing bounded sequence; hence it converges; by continuity of $f$ the limit is a fixed point; hence it's $\pi$. Since $f'(\pi)=0$ and $f''(\pi)=0$ the convergence is cubic; precisely $0 < \pi-a_ {n+1} \le (\pi- a_n)^3 /6$. $\endgroup$