This 2007 paper presents a 5-quantifier $(\in, =)$-expression that is ZF-equivalent to the axiom of choice, but leaves open the 4-quantifier case:
Thus the gap is reduced to the undecided case of a 4 quantifier sentence ZF-equivalent to AC.
Has this gap been closed?
Comments from the same paper:
All this poses the next question: “Can AC be stated by an $(\in, =)$-sentence with only 4 quantifiers?”. I personally believe this isn’t possible. This believe comes from the fact that all known (to me) sentences ZF-equivalent to AC have a form like $\forall x \ldots \exists y \phi(x, y)$. The dots allow for some premises which must be satisfied by $x$ and $\phi(x, y)$ must, in some way, express that $y$ represents a maximal decision relative to $x$. Usually this $\phi$ can’t be stated with 2 or less quantifiers. The only exception I am aware of is a reworked version of Zorn’s Lemma. But in this case the premises on $x$ become quantifier-loaded.