To convert my comments to an answer. Consider the case of convex-cocompact nonelementary subgroups $\Gamma< PSL(2,\mathbb C)$ whose domain of discontinuity in $S^2$ is nonempty (i.e. $\mathbb H^3/\Gamma$ is noncompact). Then the boundary $S$ of the convex hull of the limit set of $\Gamma$ is never a smooth surface unless it is a union of pairwise disjoint totally geodesic hyperbolic planes (which is very rarely the case). It is a "pleated surface" with $\Gamma$-invariant bending geodesic lamination $L\subset S$. The lamination $L$ is where smoothness fails. The complement $S\setminus L$ is the union of countably many convex totally geodesic regions. You can find this discussed in many details in
Epstein, D. B. A. and Marden, A. "Convex hulls in hyperbolic space, a theorem of Sullivan, and measured pleated surfaces". In: Fundamentals of hyperbolic geometry: selected expositions, 117–266. London Math. Soc. Lecture Note Ser., 328. Cambridge University Press, Cambridge, 2006
Another place where it is discussed is
Kamishima, Yoshinobu; Tan, Ser P., Deformation spaces on geometric structures, Matsumoto, Y. (ed.) et al., Aspects of low dimensional manifolds. Tokyo: Kinokuniya Company Ltd.. Adv. Stud. Pure Math. 20, 263-299 (1992). ZBL0798.53030.
and also in higher dimensions:
Kulkarni, Ravi S.; Pinkall, Ulrich, A canonical metric for Möbius structures and its applications, Math. Z. 216, No. 1, 89-129 (1994). ZBL0813.53022.
As far as I know the only solid proof of nonsmoothness (in general) is in the case of the hyperbolic 3-space. In the higher-dimensional case, examples given by "bending" of hyperbolic metrics give rise to nonsmooth boundaries of convex hulls. I do not think anything was worked out in the case of rank 1 symmetric spaces of nonconstant curvature, but I do not think there is a reason to believe they are any better than in the case of the hyperbolic space.