(Originally on MSE.)
Suppose $P$ and $Q$ are combinatorially equivalent non-self-intersecting polyhedra in $\mathbb{R}^3$, with $f$ a map from edges of $P$ to edges of $Q$ under said combinatorial equivalence. Let $\theta(e)$ be the dihedral angle of edge $e$.
If it is the case that for all $e\in D$, $\theta(e)\le \theta(f(e))$, must we have $\theta(e)=\theta(f(e))$ for all $e$?
That is, is it possible to distort the geometry of $P$ such that no dihedral angle decreases, and at least one dihedral angle increases?
My intuition is that this should not be possible, that there is some conserved notion of "total curvature" which would be violated by such an operation. But I can't seem to prove any such invariant (the sum certainly isn't one, for instance).
I'm also interested in the restriction to the convex case, ie where every dihedral angle is less than $\pi$.