Let a population $C$ consist of $N$ values $c_1, c_2, \cdots, c_N$, with $c_i\in \{0,1\}$. Let $X_1, X_2, \cdots, X_n$ denote a random sample without replacement from $C$ and let $Y_1, Y_2, \cdots, Y_n$ denote a random sample with replacement from $C$. The random variables $Y_1, \cdots, Y_n$ are independent and identically distributed with mean $\mu$ and variance $\sigma^2$, where $$ \mu=\frac{1}{N} \sum_{i=1}^N c_i, \quad \sigma^2=\frac{1}{N} \sum_{i=1}^N\left(c_i-\mu\right)^2 $$ Chernoff give upper bounds for $\Pr\{\vec{Y}-\mu \geq t\}$, where $\bar{Y}=\left(Y_1+\cdots+Y_n\right) / n$. Hoeffding proved (Theorem 4 of this paper) that the same bounds are upper bounds for $\Pr\{\bar{X}-\mu \geq t\}$, where $\bar{X}=\left(X_1\right.$ $\left.+\cdots+X_n\right) / n$.
Question
$\text { In the case above we have } E \bar{X}=E \bar{Y}=\mu \text { but } \operatorname{Var} \bar{X}=\frac{N-n}{N-1} \frac{\sigma^2}{n}<\frac{\sigma^2}{n}=\operatorname{Var} \bar{Y}$.
Doesn't variance already show how concentrated the random variables are around the mean? Why isn't it obvious that the concentration inequalities for $\bar{Y}$ would also hold for $\bar{X}$?
Now imagine instead of $n$ samples with replacement, we made $n'$ samples with replacement, for some $n'>n$. In this case, $E \bar{X}=E \bar{Y}=\mu \text, \operatorname{Var} \bar{X}=\frac{N-n}{N-1} \frac{\sigma^2}{n}, \operatorname{Var} \bar{Y}=\frac{\sigma^2}{n'}$. If we maximise $n'$ such that $\operatorname{Var} \bar{X}<\operatorname{Var} \bar{Y}$ still holds, that would yield a tighter concentration inequality.
EDIT
The following figure plots size of the sampled block vs the probability that the mean of the sample deviates from the mean of the population by a certain amount. The dots are the result from simulation. The blue line is from using Additive chernoff with $n'=n (N-1)/(N-n)$ and orange is from Serfling.
Heres the Mathematica code:
generateRandomList[n_, m_] :=
RandomSample[Join[ConstantArray[1, m], ConstantArray[0, n - m]]];
fractionGreaterThan[list_, threshold_] :=
Count[list, x_ /; x >= threshold]/Length[list];
kldFunc[x_, y_] :=
x Log[x/y] + (1 -
x) Log[(1 - x)/(1 -
y)];(*KL divergence for calculating the chernoff bound*)
n = 10^4;(*size of the population*)
p = 1 10^-1;(*Fraction of 1s in the the population*)
e = 10^-2; (*deviation from the expected value*)
biglist = generateRandomList[n, n p];
Show[{Plot[{Exp[-kldFunc[p + e, p] k ((n - 1)/(n - k))],
Exp[-2 k/(1 - (k - 1)/n) (e)^2]}, {k, 1, n},
PlotLegends -> {"Additive Chernoff - Modified", "Serf"},
AxesLabel -> {"Sampled size", "Probability"}],
ListPlot[{Table[{k, fractionGreaterThan[Table[
smallist = RandomSample[biglist, k];
Total[smallist]/k, {i, 1000}], p + e]}, {k, 1, n, 100}]},
PlotRange -> Full, PlotLegends -> {"Exact value"}]}]