Allow me to fill the details of Brendan's derivations.
We fix $0<\epsilon,\delta<1$ and show that
\begin{equation}
\frac{1}{2^{2N-2}}\sum_{k=1}^N \log k \binom{2k-2}{k-1}\binom{2N-2k}{N-k}
\ge (1-\epsilon) \left(-2+ \log N\left(1 - \frac{2\sin^{-1}\sqrt{\delta}}{\pi}\right)\right)
\end{equation}
for sufficiently large $N$. Hence, choosing small $\epsilon$ and $\delta$, we have that the limit $L$ is one, as required.
To this end, we use Stirling's approximation $\binom{2N}{N} \sim \frac{2^{2N}}{\sqrt{\pi N}}$.
In other words, for any $\epsilon > 0$, there exists $N_0$ such that
\begin{equation}
\binom{2N}{N} \geq (1-\epsilon)\frac{2^{2N}}{\sqrt{\pi N}} \text{ for $N\ge N_0$} \,.
\end{equation}
Given $\delta>0$, we then choose $M$ such that $\delta M\ge N_0 + 1$.
Hence, for all $N\ge M$ and $\delta N\le k\le (1-\delta) N$, we have that $k-1 \ge \delta M-1\ge N_0$, and so,
$\binom{2k-2}{k-1} \geq (1-\epsilon)\frac{2^{2k-2}}{\sqrt{\pi (k-1)}}$.
Similarly, $N-k\ge \delta N \ge \delta M \ge N_0$ and so,
$\binom{2N-2k}{N-k} \geq (1-\epsilon)\frac{2^{2N-2k}}{\sqrt{\pi (N-k)}}$.
Therefore, we have that
\begin{align*}
\sum_{k=1}^N \log k \binom{2k-2}{k-1}\binom{2N-2k}{N-k}
& \ge \sum_{k=\delta N}^{(1-\delta) N} \log k \Big(1-\epsilon\Big) \frac{2^{2N-2}}{\pi\sqrt{ (k-1)(N-k)}}\\
& = \frac{2^{2N-2}(1-\epsilon)}{\pi} \sum_{k=\delta N}^{(1-\delta) N} \frac{\log k}{\sqrt{ (k-1)(N-k)}}\,.
\end{align*}
Now, we estimate the sum using an integral. That is,
\begin{align*}
\sum_{k=\delta N}^{(1-\delta) N} \frac{\log k}{\sqrt{ (k-1)(N-k)}}
& =\sum_{k=\delta N}^{(1-\delta)N} \frac{\log k}{N \sqrt{(k-1)/N (1 - k /N)}}\\
&\sim \int_{\delta}^{1-\delta} \frac{\log(\lambda N)}{\sqrt{\lambda(1-\lambda)}} \,d\lambda \\
&= \int_{\delta}^{1-\delta} \frac{\log N}{\sqrt{\lambda(1-\lambda)}} \,d\lambda +\int_{\delta}^{1-\delta} \frac{\log \lambda}{\sqrt{\lambda(1-\lambda)}} \,d\lambda\\
&\ge \int_{\delta}^{1-\delta} \frac{\log N}{\sqrt{\lambda(1-\lambda)}} \,d\lambda +\int_{0}^{1} \frac{\log \lambda}{\sqrt{\lambda(1-\lambda)}} \,d\lambda\,.
\end{align*}
Now, the last inequality follows from the fact that $\log \lambda$ is negative in the interval $(0,1)$ and we have that $\int_{0}^{1} \frac{\log \lambda}{\sqrt{\lambda(1-\lambda)}} \,d\lambda = -2\pi$.
Moreover, $\int_{\delta}^{1-\delta} \frac{\log N }{\sqrt{\lambda(1-\lambda)}} \,d\lambda= (\pi-2\sin^{-1}\sqrt{\delta})\log N$.
The desired inequality then follows from standard algebraic manipulations.