My question is probably insanely hard or very well-studied, but I could not find an answer, so I will ask it here.
Assume that we have a suitably complete closed module over $\operatorname{Ho}(sSet).$ When is this category a homotopy category of a model category (with this module structure)? Clearly, there are concreteness constraints for model categories "with classifying objects" (see, e.g., this paper). However, does it mean, for example, that concrete categories can't be realized as homotopy categories? Does the problem simplify if we replace model categories with relative categories or $(\infty,1)$-categories? Maybe this is well understood for derived categories?
I understand that if we drop the assumption that there is this extra structure (like module structure or triangulation), we can take the trivial model structure. But I have no idea how to recover this extra stuff.
If this is well-studied, please point me toward some literature.