$\newcommand\Ab{\mathrm{Ab}}\newcommand\ab{\mathrm{ab}}\DeclareMathOperator\Ch{Ch}\DeclareMathOperator\Kom{Kom}\newcommand\ho{\mathrm{ho}}$Let $\Ab$ be the category of finitely generated abelian groups, $\ab$ be the subcategory with objects being the free ones, and $\Ch(\Ab)$ be the category of chain complexes over $\Ab$.
Finally, define $\Kom(\Ab) := \Ch(\Ab)/\ho$ to be the category whose objects are the same as those of $\Ch(\Ab)$, with morphisms space:
$$\Kom(\Ab)[X,Y] := \Ch(\Ab)[X,Y] \,/\, \{\text{chain-homotopy}\}.$$
I aim to tell if any two objects $X$ and $Y$ are isomorphic in $\Kom(\Ab)$.
One naïve invariant is the homology $H(-)$. Namely, if $H(X) \not \simeq H(Y)$ then $X \not\simeq Y$ in $\Kom(\Ab)$. However, this invariant is known to be "too weak" by algebraic topologists and algebraic geometers. In the context of algebraic topology, $X$ and $Y$ often are simplicial cochain complexes of some actual topological space $\tilde{X}$ and $\tilde{Y}$. There, one can study extra structures (e.g. cup products, Steenrod operations) on the homology $X$ and $Y$ to have a better chance to tell $X$ and $Y$ apart.
Question
Nevertheless, not all $X$ and $Y$ comes from an actual topological space. I wonder if there are invariants (other than homology) for objects in $\Kom(\Ab)$ (or $\Kom(\ab)$ if it is any easier).
Remarks
The same question for derived category is "trivial".
If classifying isomorphism classes in $\Kom$ turns out to be too hard, one may ask the same question for the derived categories $D(\Ab)$. Thanks to Fernando Muro's hint in the comment, I now know that taking homology is a complete invariant in our case. Essentially, this is because $\Ab$ is a hereditary category, i.e. a category $\mathcal{A}$ such that $\operatorname{Ext}_{\mathcal{A}}^2(-,-) = 0$ [3, section 1.3]. In abelian and hereditary categories $\mathcal{A}$, each bounded $X \in D(\mathcal{A})$ is isomorphic to $H(X)$ (see [3, Theorem 2.1] for a clear proof; a proof for unbounded $X$ is given in [4], but I found it confusing), and the converse is true [2].
For more general, non-hereditary categories $\mathcal{A}$, I wish to delegate the discussion to another thread "Invariants of objects in $D(\mathcal{A})$ for non-hereditary category $\mathcal{A}$" on MSE.
Related
Dror Bar-Natan's proof for that a certain chain complex (over a certain preadditive category) up to chain homotopy is an invariant of a tangle. [1]
Reference
[1] Khovanov's homology for tangles and cobordisms-[Dror Bar-Natan]
[3] Hereditary Categories. Lectures 1 and 2 - Helmut Lenzing
[4] Henning Krause’s “Derived categories, resolutions, and Brown representability”