Since outer automorphism groups of finite simple groups of Lie type are rather small solvable groups, and outer automorphisms are products of graph, field, and diagonal automorphisms in general, it should be possible to check this case by case, as @spin suggested in comments.
Using heavier machinery, it is possible to give a positive answer for "most", but not all, finite simple groups of Lie type.
If $G$ is any non-Abelian simple group whose order is divisible by the prime $p$ to the first power only, then it follows by a 2020 Theorem of Glauberman, Guralnick, Lynd and Navarro ("Centers of Sylow subgroups and automorphisms", Israel Journal of Mathematics 240, 253-266, (2020)) that the outer automorphism group of $G$ has order prime to $p$.
However, there are finite simple groups which have no Sylow subgroup of prime order, though examples are rather hard to find. It is at least known that every finite simple group has at least one cyclic Sylow subgroup, but I don't see how to apply the above result of Glauberman et al when the Sylow is cyclic of non-prime order.
Later edit: Well, I think that Glauberman et al's result shows that if a non-Abelian finite simple group $G$ has a cyclic Sylow $p$-subgroup of order $p^{n}$, then ${\rm Out}(G)$ has a cyclic Sylow $p$-subgroup of order at most $p^{n-1}$, but that is weaker than you wish for.