Let $X$ be a noetherian scheme (actually, I need the case where $X$ is proper over an affine scheme), $C$ is an object of the derived category $D_{coh}(X)$ of coherent sheaves on $X$. Under which assumptions on $C$ one can be sure that there exists a distinguished triangle (in the bigger derived category $D_{qc}(X)$ of quasi-coherent sheaves) $A\to B\to C\to A[1]$, where $A$ and $B$ are some coproducts of perfect complexes on $X$? Note that this is automatically the case if $C$ is a countable homotopy colimit of perfect complexes.
Recall that homotopy colimits of this sort were defined by Bokstedt and Neeman; it appears that they are sometimes called Milnor colimits and also coincide with "true" countable filtered homotopy colimits. Also, if $X$ is countable (in the easily defined sense) then one can easily apply certain results of Neeman to prove that a triangle as above exists for any object of $D_{qc}(X)$; hence this case is not interesting.