I will present an explicit calculation using Chern-Weil theory, which makes an amusing use of Legendre's duplication formula for the gamma function.
The Chern character form of a vector bundle $E$ with connection $\nabla$ and curvature tensor $R^\nabla$ is
$$
\mathrm{ch}(E) = \sum_{k=0}^\infty \frac{1}{k!} \mathrm{tr}(R^\nabla)^k.
$$
On the $2n$-sphere, only the $n$-th summand survives.
On a general Riemannian manifold, the curvature of the spinor bundle is
$$R^\Sigma(X, Y) \psi = \frac{1}{4}\sum_{ij=1}^m \langle R(X, Y) e_i, e_j\rangle e_i \cdot e_j,$$
where $R$ is the Riemann tensor (of the tangent bundle), $X$, $Y$ are vector fields and $e_1, \dots, e_m$ is a local ON-frame.
For the round sphere $S^m$, we have $R(X, Y) Z = \langle Y, Z\rangle X - \langle X, Z\rangle Y$, hence
$$
\sum_{ij=1}^{m}\langle R(X, Y) e_i, e_j\rangle e_i \cdot e_j
= \sum_{ij=1}^m\bigl(\langle Y, e_i\rangle \langle X e_j\rangle - \langle X, e_i\rangle \langle Y e_j\rangle\bigr)e_i \cdot e_j = X \cdot Y - Y \cdot X.
$$
We now use the general formula
$$
(\theta_1 \wedge \cdots \wedge \theta_k)(X_1, \dots, X_{2k}) = \frac{1}{2^k}\sum_{\sigma \in S_{2k}} \mathrm{sgn}(\sigma) \prod_{i=1}^k \theta_i(X_{\sigma_{2i-1}}, X_{\sigma_{2i}})
$$
for the wedge product of $2$-forms $\theta_1, \dots, \theta_k$, which can be easily shown using induction.
We then get on $S^m = S^{2n}$ that
$$
(R^\Sigma)^{2n}(e_1, \dots, e_{2n})
= \frac{1}{4^n \cdot 2^n} \sum_{\sigma \in S_{2n}} \mathrm{sgn}(\sigma) \prod_{i=1}^{n} (e_{\sigma_{2i-1}} \cdot e_{\sigma_{2i}} - e_{\sigma_{2i}} \cdot e_{\sigma_{2i-1}})\\
=\frac{1}{4^{n}} \sum_{\sigma \in S_{2n}}\mathrm{sgn}(\sigma) e_{\sigma_1} \cdots e_{\sigma_{2n}}
= \frac{(2n)!}{4^{n}} e_1 \cdots e_{2n}.
$$
Here $e_1, \dots, e_{2n}$ is a positively oriented ON-basis of the tangent space.
Because $i^{n} e_1\cdots e_{2n}$ is the grading operator of $\Sigma S^{2n}$ and the even and odd chirality spinor spaces have equal dimension, we see that it has zero trace over the whole spinor bundle.
However, the grading operator is $\pm 1$ on $\Sigma^\pm S^{2n}$, we obtain
\begin{equation*}
\mathrm{tr}_{\Sigma^\pm}(i^{n}e_1 \cdots e_{2n}) = \pm 2^{n-1},
\end{equation*}
as $\dim(\Sigma^\pm S^{2n}) = 2^{n-1}$.
We therefore get
$$
\mathrm{tr}_{\Sigma^\pm}\big((iR^\Sigma)^{n}(e_1, \dots, e_{2n})\big) = \pm \frac{(2n)!}{4^{n}} \cdot 2^{n-1} = \pm \frac{(2n)!}{2^{n+1}},
$$
which implies that
$$
\mathrm{tr}_{\Sigma^\pm}(iR^\Sigma)^{n} = \pm \frac{(2n)!}{2^{n+1}} \cdot \mathrm{vol} = \pm \frac{2n \cdot \Gamma(2n)}{2^{n+1}} \cdot \mathrm{vol} ,
$$
where $\mathrm{vol} = e_1 \wedge \cdots \wedge e_{2n}$ is the volume form.
Therefore, the $2n$-form part of the Chern character form is
$$
\mathrm{ch}_{2n}(R^{\Sigma^\pm}) = \frac{1}{n!} \mathrm{tr}_{\Sigma^\pm } \left(\frac{i R^\nabla}{2\pi}\right)^{n}
= \pm \frac{1}{n\cdot \Gamma(n)} \frac{1}{(2\pi)^{n}}\frac{2n \cdot \Gamma(2n)}{2^{n+1}} \cdot \mathrm{vol} \\
= \pm \frac{\Gamma(2n)}{ \Gamma(n)} \frac{1}{2^{2n} \pi^{n}} \cdot \mathrm{vol}.
$$
Integrating over the sphere, we get
$$
\int_{S^n} \mathrm{ch}(R^{\Sigma^\pm}) = \pm \frac{\Gamma(2n)}{ \Gamma(n)} \frac{1}{2^{2n} \pi^{n}} \cdot \underbrace{\frac{2 \pi^{(2n+1)/2}}{\Gamma\left(\frac{2n+1}{2}\right)}}_{=\mathrm{vol}(S^{2n})}
= \pm \frac{\Gamma(2n)}{\Gamma(n)\Gamma(n+1/2)} \cdot \frac{\sqrt{\pi}}{2^{2n-1}}.
$$
At this point, the right hand side looks rather hopeless, but then Legendre's duplication formula saves the day and states that the whole mess is just $\pm 1$.
Another explicit calculation can be found in these notes by Baum and Erp, see section 2.11. They realize the spinor bundle as a subbundle of a trivial bundle using a certain projection-valued function, but ultimately, the calculations are very similar and also use the duplication formula in the very last step of the proof (see the proof of Prop. 6 on p.10).